Chlorinated Tablets 1"

Trichloro‐s‐triazinetrione Boric Acid

1,3,5-trichloro-s-triazine-2,4,6-trione; TCCA; Trichlor; Symclosene; Trichloroisocyanuric Acid

Sanitizer, Disinfectant

Trichloro-s-triazinetrione……….…………98.6%

OTHER INGREDIENTS:…………………1.4%

TOTAL:…………………………………………100.0%

AVAILABLE CHLORINE…………………90%

• Appearance: White Solid Tablet/Stick

• Odor: Slight chlorine‐like

• Odor Threshold: No data available

• pH: 2.9 ‐ 3.5 @ 25°C (1% solution)

• Melting Point/Freezing Point: 478°F (248°C)

• Initial Boiling Point/Boiling Range: Not Applicable

• Flash Point: Not Applicable

• Evaporation Rate: Not Applicable

• Flammability (solid/gas): Not Flammable

• Upper/lower Flammability or Exposure limits: Not Flammable

• Vapor Pressure: <0.002 Pa @ 20°C

• Vapor Density: Not Applicable

• Density: 63 ‐ 66 lbs/ft3

• Solubility(ies): 0.98 mg/100 g @ 20 °C

• Partition Coefficient: n‐octanol/water: No data available

• Auto‐ignition Temperature: No data available

• Decomposition Temperature: 478°F (248°C)

• Viscosity: No data available

Classification:

• CORROSIVE

• FATAL IF INHALED

• HARMFUL IF SWALLOWED

• TARGET ORGAN TOXICITY (SINGLE)

• REPRODUCTIVE TOXIN

• OXIDIZER

• ENVIRONMENTAL HAZARD

Signal Word: DANGER

Hazard Statements:

HEALTH HAZARDS:

• Skin Corrosion/Irritant: Causes severe skin burns and eye damage - Category 1C

• Eye Damage/Irritation: Causes serious eye damage - Category 1

• Inhalation Toxicity: Fatal if inhaled - Category 2

• Oral Toxicity: Harmful if swallowed - Category 4

• Target Organ Toxicity (single exposure) May cause respiratory tract irritation - Category 3

• Reproductive Toxin - May damage fertility or the unborn child - Category 1B.

PHYSICAL HAZARDS: Oxidizing Solid - May intensify fire; oxidizer - Category 2 - OXIDIZING AGENT. Contact with water slowly liberates irritating and hazardous chlorine containing gases. Contamination with moisture, organic material, or other incompatible chemicals may start a reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion. Contact with acids liberates toxic gas. Decomposes at temperatures above 464°F with liberation of harmful gases. When ignited will burn with the evolution of chlorine and equally toxic gases. Do not get water inside container. Wet material may generate nitrogen trichloride, an explosion hazard.

ENVIRONMENTAL HAZARDS:

• Very toxic to aquatic life - Acute 1

• Very toxic to aquatic life with long lasting effects - Chronic 1.

Do not breathe dust, fume, gas, mist, vapors, or spray. In case of inadequate ventilation, wear respiratory protection. Wear protective gloves, protective clothing, eye, and face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Keep container tightly closed and store locked up. Avoid release to the environment.

May intensify fire, oxidizer. Keep away from heat.

ADDITIONAL HAZARD INFORMATION: This material is corrosive. Product has strong buffering capability. Use dilution. May cause burns to moist skin if not promptly removed. There is no specific antidote.

OSHA permissible exposure limit: Regulatory Exposure Limit(s): None. This product does not contain any components that have regulatory occupational exposure limits (OEL's) established.

• OEL: Occupational Exposure Limit; OSHA: United States Occupational Safety and Health Administration;

• NON-REGULATORY EXPOSURE LIMIT(S): None. This product does not contain any components that have advisory (non-regulatory) occupational exposure limits (OEL's).

• The Non-Regulatory United States Occupational Safety and Health Administration (OSHA) limits, if shown, are the Vacated 1989 PEL's (vacated by 58 FR 35338, June 30, 1993).

• The American Conference of Governmental Industrial Hygienists (ACGIH) is a voluntary organization of professional industrial hygiene personnel in government or educational institutions in the United States. The ACGIH develops and publishes recommended occupational exposure limits each year called Threshold Limit Values (TLVs) for hundreds of chemicals, physical agents, and biological exposure indices. Additional Advice: Chlorine and chlorine compounds may be found in slight amounts in the head space of containers of this product.

• Stability/Reactivity: Stable under normal temperatures and pressures. NPFA Class 1 Oxidizer.

• Possibilities of Hazardous Reactions: Hazardous Polymeriza􀆟on: Will Not Occur

• Incompatible Materials: Acids, ammonia, bases, floor sweeping compounds, calcium hypochlorite, reducing agents, organic solvents and compounds.

• Hazardous Decomposition Materials: Chlorine, Nitrogen, Nitrogen trichloride, Cyanogen chloride, Oxides of carbon, Phosgene.

TSCA: USA: Reported in the EPA TSCA Inventory or are exempt.

Right To Know Hazardous Substance List:

• California Proposition 65: This product is not listed

• Massachusetts Right to Know Hazardous Substance List Listed

• New Jersey Right to Know Hazardous Substance List: 1892

• New Jersey Special Health Hazards Substance List Not Listed

• New Jersey - Environmental Hazardous Substance List Not Listed

• Pennsylvania Right to Know Hazardous Substance List Listed

• Pennsylvania Right to Know Special Hazardous Substances Not Listed

• Pennsylvania Right to Know Environmental Hazard List Not Listed

• Rhode Island Right to Know Hazardous Substance List Listed

Workplace Classification: This product is considered hazardous under the OSHA Hazard Communication Standard (29CFR 1910.1200).

EPA NOTES: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. Following is the hazard information as required on the pesticide label: SIGNAL WORD: DANGER

PRECAUTIONARY STATEMENTS. HAZARDS TO HUMANS AND DOMESTIC ANIMALS. DANGER. CORROSIVE. Causes irreversible eye damage. May be fatal if inhaled. Harmful if swallowed or absorbed through the skin. Do not breathe dust, vapor or spray mist. Wear goggles, face shield or safety glasses. Wash thoroughly with soap and water after handling and before eating, drinking or using tobacco. Remove contaminated clothing and wash before reuse.

PHYSICAL AND CHEMICAL HAZARDS: Strong oxidizing agent: DO NOT mix with other chemicals. Mix only with water. Never add water to product. Always add product to large quantities of water. Use clean, dry utensils. Do not add this product to any dispensing device containing remnants of any other product. Such use may cause a violent reaction leading to fire or explosion. Contamination with moisture, organic matter or other chemicals will start a chemical reaction and generate heat, hazardous gas, possible fire and explosion. In case of contamination or decomposition, do not reseal container. If possible, isolate container in open air, well ventilated area. Flood area with large volumes of water.

ENVIRONMENTAL HAZARDS: This product is toxic to fish and aquatic organisms.

BIODEGRADATION: This material is subject to hydrolysis. Cyanuric acid produced by hydrolysis is biodegradable.

PERSISTENCE: This material is believed not to persist in the environment. Free available chlorine is rapidly consumed by reaction with organic and inorganic materials to produce chloride ion. The stable degradation products are chloride ion and cyanuric acid.

BIOCONCENTRATION: This material hydrolyses in water liberating free available chlorine and cyanuric acid. These products are not bioaccumulative. This product is toxic to fish and aquatic organisms.

ADDITIONAL ECOLOGICAL INFORMATION: This product is very toxic to fish and aquatic organisms. This product is very toxic to aquatic life with long lasting effects. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.