KEEP OUT OF REACH OF CHILDREN.
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Product name: Silver Mineral Formula with Clarifier
Synonyms; trade names: POOL FROG Mineral Reservoir
EPA Registration Number: 53735-11
Application: Pool water conditioner
Uses advised against: Use only for intended applications
Supplier:
King Technology, Inc.
6000 Clearwater Dr.
Minnetonka Mn 55343
United States
1+ (952) 933-6118
Emergency Phone Number: CHEMTREC 800-424-9300 (24 hours)
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Classification of the substance or mixture
OSHA Regulatory Status: The below environmental hazard classification is non-mandatory under the OSHA Hazard Communication Standard. The environmental classification is according to the UN Globally Harmonized System of Classification and Labeling of Chemicals (GHS), 8th revised edition, 2019.
Physical hazards: Met. Corr. 1-H290
Health Hazards: Skin Corr. 1A-H314 Eye Dam. 1-H318
Environmental Hazards: Aquatic Acute 1-H400 Aquatic Chronic 1-H410
Single Word: Danger
Hazard Statements:
May be corrosive to metals
Causes severe skin burns and eye damage
Very toxic to aquatic life with long lasting effects
May be corrosive to metals
Causes severe skin burns and eye damage
Causes serious eye damage
Very toxic to aquatic life
Very toxic to aquatic life with long lasting effects
Precautionary Statements
Keep only in original container
Do not breath dust
Wash contaminated skin throughly after handling
Avoid release to the environment
Wear protective gloves /protective clothing / eye protection / face protection
If swallowed: Rinse mouth. DO NOT induce vomiting
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water / shower
If inhaled: Remove person to fresh air and keep comfortable for breathing
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center / doctor
Specific treatment (see medical advice on the label of the product
Wash contaminated clothing before reuse
Absorb spillage to prevent material damage
Collect spillage
Store locked up
Store in corrosive resistant container with a resistant inner liner
Dispose of contents / container in accordance with national regulations
Contains: Aluminum Sulfate
Other Hazards
Other: No additional hazards known. «46»% of the mixture consists of ingredient(s) of unknown acute toxicity
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Mixtures
Calcium Carbonate
CAS number: 471-34-1
80%-90%
Classification: Not classified
Aluminum Sulfate
CAS number: 10043-01-3
10%-20%
Classification:
Met. Corr. 1-H290
Skin Corr. 1A-H314
Eye Dam. 1-H318
Silver Chloride
CAS number: 7783-90-6
<1%
M Factor (Acute) =1000
M Factor (Chronic) = 100
Ingredient Notes: The exact percentage/concentration is withheld as a trade secret in accordance with 29 CFR 1910.1200
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Description of first-aid measures
General information:: Get medical attention if any discomfort continues. Show this webpage to the medical personnel. Chemical burns must be treated by a physician
Inhalation: Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as collar, tie, or belt. Rinse nose and mouth with water. Never give anything by mouth to an unconscious person. Get medical attention if symptoms are severe or persists.
Ingestion: Rinse mouth thoroughly with water. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Get medical attention.
Skin Contact: It is important to remove the substance from the skin immediately. Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes and get medical attention. Chemical burns must be treated by a physician.
Eye Contact: Rinse immediately with plenty of water. Do not rub eye. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.
Protection of first aiders: It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation.
Most important symptoms and effects, both acute and delayed
General Information: The severity of the symptoms described will vary dependent on the concentration and the length of exposure.
Inhalation: A single exposure may cause the following adverse effects: Severe irritation of nose and throat. Symptoms following overexposure may include the following: Corrosive to the respiratory tract.
Ingestion: May cause chemical burns in mouth, esophagus and stomach. Symptoms following overexposure may include the following: Severe stomach pain. Nausea, vomiting.
Skin Contact: Causes severe burns. Symptoms following overexposure may include the following: Pain or irritation. Redness. Blistering may occur.
Eye Contact: Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness.
Indication of immediate medical attention and special treatment needed
Notes for the doctor: Treat symptomatically
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Extinguishing media
Suitable extinguishing media: The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.
Hazardous combustion products: Thermal decomposition or combustion products may include the following substances: Very toxic or corrosive gases or vapors.
Advice for Firefighters
Protective actions during firefighting: Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of gases, vapors, fumes, and smoke. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Avoid discharge tot he aquatic environment. Control run-off water by containing and keeping it our of sewers and watercourses. IF risk of water pollution occurs, notify appropriate authorities.
Special protective equipment for firefighters: Regular protections may not be safe. Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective boots and gloves will provide a basic level of protection for chemical incidents.
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Personal precautions, protective equipment and emergency procedures
Personal Precautions: Wear protective clothing as described in the Exposure controls/Personal protection tab of this webpage. No action shall be taken without appropriate training in involving any personal risk. Do not touch or walk into spilled material. Avoid inhalation of dust. Use suitable respiratory protection if ventilation is inadequate. Avoid contact with skin and eyes.
Environmental Precautions
Environmental Precautions: Avoid discharge into drains or watercourses or onto the ground. Avoid discharge tot he aquatic environment.
Methods and Material for Containment and Cleaning Up
Methods for cleaning up: Wear protective clothing as described in the Exposure controls/Personal protection tab on this webpage. Clear up spills immediately and dispose of waste safely. This product is corrosive. Collect spillage with a shovel and broom. or similar and reuse, if possible. Collect and place in suitable water disposal containers and seal securely. Flush contaminated area with plenty of water. Wash throughly after dealing with a spillage. Dangerous for the environment. Do not empty into drains For water disposal, see the Disposal Considerations tab on this webpage.
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Precautions for safe handling
Usage Precautions: Keep out of reach of children. Read and follow manufacturer’s recommendations. Wear protective clothing as described in the next tab. Keep away from food, drink, and animal feeding stuff. Keep container tightly sealed when not in use. This product is corrosive. Immediate first aid is imperative. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers.
Advice on general occupational hygiene: Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash before use. Wash contaminated clothing before reuse.
Conditions for safe storage, including any incompatibilities
Storage Precautions: Store away from incompatible materials (see the Stability and reactivity tab). Store locked up. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Store in corrosive resistant container with a resistant inner liner.
Storage Class: Corrosive storage.
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Control Parameters
Occupational Exposure Limits
Calcium carbonate (CAS 471-34-1)
OSHA permissible Exposure Limit (PEL): TWA 15 mg/m3 (total dust)
OSHA permissible Exposure Limit (PEL): TWA 5 mg/m3 (respirable dust)
NIOSH Recommended Exposure Limit (REL: TWA 10 mg/m3 (total dust)
NIOSH Recommended Exposure Limit (REL: TWA 5 mg/m3 (respirable dust)
Aluminum Sulfate (CAS 7783-90-6)
US ACGIH. CAS 10043-01-3. Threshold limit value (TL-TWA): 1 mg/mg3
Silver Chloride (CAS 7783-90-6)
OSHA Permissible Exposure Limit (PEL): TWA 0.01 mg/m3 (Silver soluble compounds, as Ag)
NOISH Immediately Dangerous to Life or Health (IDLH): TWA 10 mg/m3 (Silver soluble compounds, as Ag)
NOISH Recommended Exposure Limit (REL): TWA 0.01 mg/m3 (Silver soluble compounds, as Ag)
ACGIH Threshold Limit Value (TLV): 0.1 mg/m3 (Silver soluble compounds, as Ag)
Exposure Controls
Appropriate Engineering Controls: Provide adequate ventilation. Observe any occupational exposure limits for the product or ingredients.
Eye/Face Protection: Wear tight-fitting, chemical splash goggles or face shield. If inhalation hazards exists, a full-face respirator may be required instead.
Hand Protections: Wear protective gloves. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical and resistant degradation. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended.
Other Skin and Body Protection: Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene Measures: Wash after use and before eating, smoking, and using the toilet. Do not eat, drink, or smoke when using this product.
Respiratory Protection: Ensure all respiratory protective equipment is suitable for its intended use and is NOISH approved. Check that the respirator fits tightly and the filter is changes regularly. Gas and combination filter cartridges should comply with OSHA 1910.134. Full face mask respirators with replaceable filter cartridges should comply with OSHA 1910.134. Half mask and quarter mask respirators with replaceable filter cartridges should comply with OSHA 1910.134.
Environment Exposure Controls: Keep container tightly sealed when not is use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
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Appearance: Granules
Color: White
Odor: Oderless
No other information available
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Reactivity: May be corrosive to metals
Stability: Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions.
Possibility of hazardous reactions: No potentially hazardous reactions known
Conditions to avoid: Keep away from heat, sparks and open flame
Materials to avoid: Water, moisture. Mild steel. Stainless steel. Aluminum. May be corrosive to metals.
Hazardous decomposition products: Does not decompose when used and stores as recommended. Thermal decompositions or combustion products may include the following substances: Corrosive gases or vapors.
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Information on toxicological effects
Acute toxicity - oral
Notes (oral lD50) Based on available data classification criteria are not met.
Acute toxicity - dermal
Notes (dermal lD50) Based on available data classification criteria are not met.
Acute toxicity - inhalation
Notes (inhalation lD50) Based on available data classification criteria are not met.
Skin corrosion/irritation
Summary: Prolonged contact with moist or wet product may cause burns.
Skin corrosion/irritation: Skin Corr. 1-H314 Causes burns.
Serious eye damage/irritation
Serious eye damage/irritation: Eye Dam. 1-H318 Corrosive to skin. Corrosively to eyes is assumed.
Respiratory sensitization
Respiratory sensitization: Based on available data the classification criteria are not met.
Skin Sensitization
Skin Sensitization: Based on available data the classification criteria are not met.
Gem cell mutagenicity
Gem cell mutagenicity: Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity: Based on available data the classification criteria are not met.
IARC carcinogenicity: None of the ingredients are listed.
NTP carcinogenicity: None of the ingredients are listed.
OSHA carcinogenicity: None of the ingredients are listed.
Reproductive toxicity
Reproductive toxicity-fertility: Based on available data the classification criteria are not met.
Reproductive toxicity-development: Based on available data the classification criteria are not met.
Specific target organ toxicity - single exposure
STOT - single exposure: Not classified as a specific target organ toxicant after a single exposure.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure: Not classified as a specific target organ toxicant after a repeated exposure.
Aspiration hazard
Aspiration hazard: Not relevant. Solid.
General information: The severity of the symptoms described will vary dependent on the concentration and the length of exposure
Inhalation: Corrosive to he respiratory tract. Symptoms following overexposure may include the following: Severe irritation of nose and throat.
Ingestion: May cause chemical burns in mouth, esophagus and stomach. Symptoms following overexposure may include the following: Severe stomach pain, Nausea, vomiting
Skin Contact: Causes severe burns. Symptoms following overexposure may include the following: Pain or irritation. Redness. Blistering may occur
Eye contact: Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness
Route of exposure: Ingestion inhalation Skin and/or eye contact
Target Organs: No specific target organs known
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Toxicity: Very toxic to aquatic life with long lasting effects
Persistence and degradability: The degradability of the product is not known
Bio-Accumulative potential: No data available on bioaccumulation
Partition coefficient: No information available
Mobility in soil: No data available
Other adverse effects: None known
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General information: The generation of waste should be minimized or avoided whenever possible. Reuse or recycle products whenever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentiality hazardous.
Disposal methods: Do not empty in drains.. Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste, residues, empty containers, discarded work cloths and contaminated cleaning materials should be collected in designated containers, labeled with their contents. Incineration or landfill should only be considered when recycling is not feasible.
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United States FIFRA-Pesticide labeling: This product is a US EPA FIFRA registered pesticide (EPA Reg, No.: 53735-11) and is subject to certain labeling requirements under federal pesticide law. These requirements may differ from the classification criteria and hazard information for an OSHA GHS SDS. The following is the hazard information as required on the FIFRA label:
Single Word: CAUTION
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities: Not applicable
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA): The following ingredients are listed:
Silver compounds
No RQ assigned
Aluminum Sulfate
Final CERCLA RQ: 5000(2270) pounds (kilograms)
SARA Extremely Hazardous Substances EPCRA Reportable Qualities: Not applicable
SARA 313 Emission Reporting: No applicable
CAA Accidental Release Prevention: Not applicable
FDA-Essential Chemical: Not applicable
FDA-Precursor Chemical: Not applicable
SARA (311/312) Hazard Categories: Skin corrosion or irritation
OSHA Highly Hazardous Chemicals: Not applicable
US Clean Water Act-Section: The following ingredients are listed: Silver compounds
307 (a)(1) Toxic Pollutants
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxics: None of the ingredients are listed.
California Air Toxics “Hot Spots” (A-I): Not applicable
California Air Toxics “Hot Spots” (A-II): Not applicable
California Directors List of Hazardous Substances: The following ingredients are listed: Silver compounds
California Hazardous Waste: The following ingredients are listed: Silver compounds
Control Law
Massachusetts “Right To Know” List: Not applicable
Rode Island “Right To Know” List: Not applicable
Minnesota “Right To Know” List: Not applicable
New Jersey “Right To Know” List: Not applicable
Pennsylvania“Right To Know” List: Not applicable
Colorado Hazardous Waste: The following ingredients are listed: Silver compounds
Regulation Appendix VII
Hazardous Waste
Constituents
Louisiana Reportable Quantity: The following ingredients are listed: Silver compounds
List for pollutants: No RQ Assigned
New Jersey Discharge Tax: The following ingredients are listed: Silver compounds
List of hazardous Substances:
Massachusetts Oil and Hazardous Materials List: The following ingredients are listed: Silver compounds RQ: (50 lbs)
Inventories
US0TSCA
All ingredients are listed or exempt.
Calcium Carbonate
Aluminum Sulfate
US-TSCA 12(b) Export Notification: Not applicable