NATURAL CHEMISTRY SPA PURGE

Product Name: NATURAL CHEMISTRY SPA PURGE

Recommended Use: Water Cleaning Compound and Phosphate Remover.

Uses advised against: Do not mix with other chemicals

OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation: Category 2

Skin sensitization: Category 1

Emergency Overview

• Warning Hazard Statements

• Causes serious eye irritation

• May cause an allergic skin reaction

• Color: amber

• Physical state:

  Liquid

• Odor: No information available

Precautionary Statements - Prevention: Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe mist or vapor. Contaminated work clothing should not be allowed out of the workplace

• IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention

• IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse

Precautionary Statements - Storage: Keep out of reach of children. Store away from incompatible materials.

Precautionary Statements - Disposal: Dispose of contents/containers in accordance with local regulations

Hazards not otherwise classified (HNOC): Not applicable

Other Information: 1.84% of the mixture consists of ingredient(s) of unknown toxicity

OSHA Hazard Classification: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Alcohols, C9-11, ethoxylated

• CAS No.: 68439-46-3

• Weight-%: 1 - 5

Hexahydro-1,3,5-tris(2-hydroxyethyl)-S-triazine

• CAS No.: 4719-04-4

• 0.1 - 1

• Physical state: Liquid

• Appearance: cloudy

• Color: amber

• Odor: No information available

• Odor threshold: No information available

• pH: 5.7 - 6.7

• Specific Gravity: 1 - 1.01

• Density: 8.3 - 8.5 lb/gal

• Explosive properties: Not explosive

• Oxidizing properties: Not oxidizing.

Eye contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If symptoms persist, call a physician.

Skin contact: Wash off immediately with plenty of water for at least 15 minutes. Wash contaminated clothing before reuse. If skin irritation persists, call a physician.

Inhalation: Remove to fresh air. If symptoms persist, call a physician.

Ingestion: Do NOT induce vomiting. Rinse mouth. Drink plenty of water. If large quantities are swallowed, call a physician immediately.

Self-protection of the first aider: Use personal protective equipment as required.

Symptoms: Eye contact: There may be irritation and redness.

Note to physicians: May cause sensitization in susceptible persons. Treat symptomatically.

Suitable extinguishing media: Dry chemical. Carbon dioxide (CO2). Water spray (fog). Foam.

Unsuitable extinguishing media: None known.

Specific hazards arising from the chemical: In the event of fire and/or explosion do not breathe fumes. May cause sensitization in susceptible persons. Thermal decomposition can lead to release of irritating and toxic gases and vapors.

Hazardous combustion products: Carbon oxides.

Explosion data

• Sensitivity to Mechanical Impact: None.

• Sensitivity to Static Discharge: None.

Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Personal precautions: Use personal protective equipment as required. Avoid contact with eyes and skin. Keep people away from and upwind of spill/leak. Ensure adequate ventilation, especially in confined areas.

Environmental precautions: See the Ecological Information tab for additional ecological information. Avoid release to the environment.

Methods for containment: Prevent further leakage or spillage if safe to do so. Dike far ahead of spill; use dry sand to contain the flow of material.

Methods for cleaning up: Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. After cleaning, flush away traces with water. Prevent product from entering drains. Dispose of contents/containers in accordance with local regulations.

Advice on safe handling: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. Handle in accordance with good industrial hygiene and safety practice.

Storage Conditions: Keep out of the reach of children. Keep container tightly closed. Keep containers tightly closed in a cool, well-ventilated place.

Incompatible materials: Acids. Strong oxidizing agents. Do not mix with other swimming pool/spa chemicals in their concentrated forms.

Exposure Guidelines: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.

Engineering Controls

• Showers

• Eyewash stations

• Ventilation systems.

Eye/face protection: Wear safety glasses with side shields (or goggles).

Skin and body protection: Wear protective gloves and protective clothing.

Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

General Hygiene Considerations: When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Wash hands thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice.

Reactivity: This product may react with strong oxidizing agents.

Chemical stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: None under normal processing.

Conditions to avoid: Extremes of temperature and direct sunlight.

Incompatible materials: Acids. Strong oxidizing agents. Do not mix with other swimming pool/spa chemicals in their concentrated forms.

Hazardous Decomposition Products: May produce the following when heated:. Carbon oxides.

Inhalation: Not an expected route of exposure.

Eye contact: Causes serious eye irritation.

Skin contact: May cause sensitization by skin contact.

Ingestion: May be harmful if swallowed.

Symptoms: Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Skin corrosion/irritation: Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation: Causes serious eye irritation.

Sensitization: May cause sensitization by skin contact.

Chronic toxicity: Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure.

Ecotoxicity: 2.46562% of the mixture consists of components(s) of unknown hazards to the aquatic environment

Persistence and degradability: No information available.

Bioaccumulation: No information available.

Mobility: No information available.

Other adverse effects: No information available

Disposal of wastes: Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging: Do not reuse container. Refer to all federal, state and local regulations prior to disposal of container and unused contents by reuse, recycle or disposal.

TSCA: Complies

DSL/NDSL: Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

• Acute health hazard: Yes

• Chronic Health Hazard: Yes

• Fire hazard: No

• Sudden release of pressure hazard: No

CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

California Proposition 65: This product does not contain any Proposition 65 chemicals

EPA Pesticide Registration Number: This product does not contain any substances regulated as pesticides

Difference between SDS and CPSC label: This product is regulated under Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act (16 CFR Part 1500) . These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace product labels.

NFPA

• Health hazards: 1

• Flammability: 0

• Instability: 0

• Physical and Chemical Properties: -

HMIS

• Health hazards: 1*

• Flammability: 0

• Physical hazards: 0

• Personal protection: X